Dibromidobis(N,N-diethyldithiocarbamato-κ2 S,S′)tetra-μ3-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
نویسندگان
چکیده
The mol-ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu-μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O-H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).
منابع مشابه
Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ3-sulfido-dimolybdenum(V)dicopper(I)
The title compound, (C(8)H(20)N)(2)[Cu(2)Mo(2)(C(2)H(4)S(2))(2)(CN)(2)S(4)], is a sulfide-bridged tetranuclear complex in which the complex anion comprises one [(edt)(2)Mo(2)S(2)(μ-S)(2)](2-) unit (edt = ethanedithiol-ate) and two CuCN units joined through six Cu-μ(3)-S bonds, thus forming a cubane-like [Mo(2)S(4)Cu(2)] core. There are two independent cation-anion complex entities in the asymme...
متن کاملThe mixed-valent copper thiolate complex hexakis{μ3-2-[(1,3-dimethylimidazolidene)amino]benzenethiolato}dicopper(II)tetracopper(I) bis(hexafluoridophosphate) acetonitrile disolvate dichloromethane disolvate
The mol-ecular structure of the title compound, [Cu4(I)Cu2(II)(C11H14N3S)6](PF6)2·2CH3CN·2CH2Cl2, shows a mixed-valent copper(I/II) thiol-ate complex with a distorted tetra-hedral coordination of the Cu(I) and Cu(II) cations by one guanidine N atom and three S atoms each. Characteristic features of the Cu6S6 skeleton are a total of six chemically identical μ3-thiol-ate bridges and almost planar...
متن کاملA tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands
The asymmetric unit of the title complex, [Ag(4)W(2)S(8)(C(25)H(22)P(2))(3)]·2C(3)H(7)NO, tris-[μ(2)-bis-(diphenyl-phosphino)meth-ane]-3:6κ(2)P:P';4:5κ(2)P:P';5:6κ(2)P:P'-μ(5)-sulfido-2:3:4:5:6κ(5)S-μ(3)-sulfido-1:3:4κ(3)S-tetra-μ(2)-sulfido-1:3κ(2)S;1:4κ(2)S;2:5κ(2)S;2:6κ(2)S-disulfido-1κS,2κS-tetra-silver(I)ditungsten(VI) N,N-dimethyl-formamide disolvate, contains two [WS(4)](2-) anions, four...
متن کاملcatena-Poly[di-μ3-bromido-hexa-μ2-bromido-dibromidobis(O-methyl pyridine-2-carboximidate-κ2 N,N′)pentamercury(II)]
The title compound, [Hg5Br10(C7H8N2O)2] n , contains two μ3-bridging Br atoms, six μ2-bridging Br atoms and two terminal Br atoms. One Hg(II) atom, lying on an inversion center, adopts a distorted octa-hedral geometry defined by six Br atoms. Two Hg(II) atoms adopt a distorted square-pyramidal geometry by five Br atoms and the other two Hg(II) atoms have a distorted tetra-hedral geometry by two...
متن کاملPoly[[μ2-1,2-bis(4-pyridyl)ethene-κ2 N:N′]-di-μ3-bromido-dicopper(I)]
In the title polymeric Cu(I) compound, [Cu(2)Br(2)(C(12)H(10)N(2))](n), the Cu cation is coordinated by an N atom from the 1,2-bis-(4-pyrid-yl)ethene ligand and three Br(-) anions in a distorted tetra-hedral CuBr(3)N coordination geometry. Each Br(-) anion bridges three Cu cations related by inversion centers, forming a stair-like polymeric chain along the a axis, and the terminal N atoms of th...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008